By Edited by Pietro VINCENZINI World Academy of Ceramics and National Research Council, Italy Co-edited by James P. BENNETT NETL – USDOE, USA
Read Online or Download 12th INTERNATIONAL CERAMICS CONGRESS PART I Proceedings of the 12 th International Ceramics Congress, part of CIMTEC 2010- 12 th International Ceramics Congress and 5th Forum on New Materials Montecatini Terme, Italy, June 6-11, 2010 PART I including: Sym PDF
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Extra resources for 12th INTERNATIONAL CERAMICS CONGRESS PART I Proceedings of the 12 th International Ceramics Congress, part of CIMTEC 2010- 12 th International Ceramics Congress and 5th Forum on New Materials Montecatini Terme, Italy, June 6-11, 2010 PART I including: Sym
Complementary studies have been conducted on the thermomechanical behavior of such materials. Their results allow proposing a synthetic diagram to describe the evolutions of their behavior as a function of the considered temperature level. Such a description is given in figure 1 where three temperature domains have been defined. In the low temperature domain, the behavior is mainly a damage elastic one whereas the behavior is elasto-viscoplastic in the high temperature domain. These two domains are separated by a transition domain whom boundaries can vary in the 8001000°C temperature range, depending on the material formulation.
This system is still suitable for raw materials control and under fixed conditions, may be used for castables quality control. Indeed, the presence of aggregates induces a lower cement content of the mix, and thus limits the overall temperature increase. Under these conditions, it is possible to approach real castables conditions for CA hydrates precipitations which are strongly temperature dependent. In the castable system, the heat release is sometimes very small. 5%. In order to enable the detection of the exothermic peak, large and well insulated samples must be used.
Change of crack path in case of brittleness reduction may even be observed for one and the same refractory with increasing temperature. This is exemplified by measurements B and H. The relatively brittle pure magnesia material shows a decrease of lC,GG which falls from 23,0 % at room temperature to 10,5% at 1100°C. In case of less brittle magnesia spinel material C lC,GG does not decrease further, but lC,GM increases form 49,7 % to 57,8 % at the expense of lC,MM (lC,GG slightly increases from room temperature to 1100°C which might not be significant).